FROM WAYNE STATE UNIVERSITY

2017

109. I. K. Hewavitharana and S. L. Brock, "When Ligand Exchange Leads to Ion Exchange: Nanocrystal Facets Dictate the Outcome" ACS Nano, 2017.  http://pubs.acs.org/doi/abs/10.1021/acsnano.7b05534
 
 
108. D. Liyanage, D. Li, Q. B. Cheek, H. Baydoun, S. L. Brock, "Enhanced Activity by Dilution of the Noble Metal: Synthesis and Oxygen Evolution Reaction (OER) Catalytic Performance of Ni2-xRuxP nanocrystals" Journal of Material Chemistry A, 2017, Accepted

107. L. Korala, J. Germain, E. Chen, I. Pala, D. Li and S. L. Brock, "CdS Aerogels as Efficient Photocatalysts for Degradation of Organic Dyes under Visible Light Irradiation " Inorganic Chemistry Frontiers, 2017, Advance Article http://pubs.rsc.org/en/content/articlehtml/2017/qi/c7qi00140a

106. J. Davis, A. Chalifoux, S. L. Brock, "Role of Crystal Structure and Chalcogenide Redox Properties on the Oxidative Assembly of Cadmium Chalcogenide Nanocrystals" Langmuir, 2017, Article ASAP. http://pubs.acs.org/doi/full/10.1021/acs.langmuir.7b01118

105. R. Pimmachcharige, Y. Zhang, R. Regmi, G. Lawes and S. L. Brock, "Solution-Phase Growth Mechanism of Phosphours-doped MnAs Nanoparticles: Size, Polydispersity, and Dopant Control on the Nanoscale " Journal of Materials Chemistry C, 2017, 5, 3352-3358. http://pubs.rsc.org/en/Content/ArticleLanding/2017/TC/C7TC00579B#!divAbstract

104. D. Li, H. Baydoun,  B. Kulikowsk, S. L. Brock, "Boosting Catalytic Performance of Iron Phosphide Nanorods for the Oxygen Evolution Reaction by Incorporation of Manganese" Chemistry of Materials, 2017, Accepted. http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.7b00055

2016

103. M. Hettiarachchi, E. Abdellhamid, B. Nadgorny, S. L. Brock, "Synthesis of Colloidal MnSb Nanoparticles: Consequences of Size and Surface Characteristics on Magnetic Properties. Journal of Materials Chemistry C, 2016, 4, 6790-6797.  http://pubs.rsc.org/en/content/articlelanding/2016/tc/c6tc01478j#!divAbstract

 

102. D. Li, M. P. Arachchige, B. Kulikowski, G. Lawes, T. Seda, S. L. Brock, "Control of Composition and Size in Discrete CoxFe2-xP Nanoparticles: Consequence for Magnetic Properties" Chemistry of Materials, 2016, 28, 3920-3927. http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.6b01185

101. D. Li, H. Baydoun, C. N. Verani, S. L. Brock, "Efficient Water Oxidation Using CoMnP Nanoparticles" Journal of the American Chemical Society, 2016, 138, 4006-4009. http://pubs.acs.org/doi/abs/10.1021/jacs.6b01543

100. S. Danforth, D. Liyanage,  A. Hitihami-Mudiyanselage, B. Ilic, S. L. Brock, M. Bussell “Probing hydrodesulfurization over bimetallic phosphides using monodisperse Ni2-xMxP nanoparticles encapsulated in mesoporous silica” Surface Science,  2016, 648, 126-135 http://www.sciencedirect.com/science/article/pii/S003960281500309X

2015

99. D. James, X. Lu, D. Morelli, S. L. Brock “Solvothermal Synthesis of Tetrahedrite: Speeding Up the Process of Thermoelectric Material Generation” ACS Appl. Mater. Interface, 20157, 23623–23632 http://pubs.acs.org/doi/abs/10.1021/acsami.5b07141

98. A. Hitihami-Mudiyanselage, M. Arachchige, T. Seda, G. Lawes, S. L. Brock “Synthesis and Characterization of Discrete FexNi2–xP Nanocrystals (0 <x < 2): Compositional Effects on Magnetic Properties” Chemistry of Materials, 201527, 6592–6600 http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.5b02149

97. D. Li, K. Senevirathne, L. Aquilina, S. L. Brock  “Effect of Synthetic Levers on Nickel Phosphide Nanoparticle Formation: Ni5P4 and NiP2” Inorganic Chemistry, 2015, 54, 7968-7975  http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.5b01125

96. D. Liyanage, S. Danforth, Y. Liu, M. Bussell,  S. L. Brock “Simultaneous Control of Composition, Size, and Morphology in Discrete Ni2–xCoxP Nanoparticles” Chemistry of Materials, 2015, 27, 4349-4357  http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.5b00958

95. D. James, X. Lu, A. Nguyen, D. Morelli, S. L. Brock “Design of Lead Telluride Based Thermoelectric Materials through Incorporation of Lead Sulfide Inclusions or Ligand Stripping of Nanosized Building Blocks” The Journal of Physical Chemistry C, 2015, 119, 4635-4644  http://pubs.acs.org/doi/abs/10.1021/jp5127046

 

2014

94. A. Hitihami-Mudiyanselage, K. Senevirathne, S. L. Brock “Bottom-Up Assembly of Ni2P Nanoparticles into Three-Dimensional Architectures: An Alternative Mechanism for Phosphide Gelation” Chemistry of Materials, 2014, 26, 6251-6256 http://pubs.acs.org/doi/abs/10.1021/cm5030958

93. Y. Zhang, R. Regmi, Y. Liu, G. Lawes, S. L. Brock "Phase-Coexistence and Thermal Hysteresis in Samples Comprising Adventitiously Doped MnAs Nanocrystals: Programming of Aggregate Properties in Magnetostructural Nanomaterials” ACS Nano 2014, 8, 6814-6821 http://pubs.acs.org/doi/full/10.1021/nn501149s   

 

2013

92. G. H. L. Savithra, R. H. Bowker, Bo A. Carrillo, M. E. Bussell, S. L. Brock “Mesoporous Matrix Encapsulation for the Synthesis of Monodisperse Pd5P2 Nanoparticle Hydrodesulfurization Catalysts”ACS Applied Materials and Interfaces 2013, 5, 5403-5407 http://pubs.acs.org/doi/abs/10.1021/am402003g

91. G. H. L. Savithra, E. Muthuswamy, R. H. Bowker, Bo A. Carrillo, M. E. Bussell, S. L. Brock “Rational Design of Nickel Phosphide Hydrodesulfurization Catalysts: Controlling Particle Size and Preventing Sintering”Chemistry of Materials 2013, 25, 825–833 http://pubs.acs.org/doi/abs/10.1021/cm302680j

90. L. Korala, Z. Wang, Y. Liu, S. Maldonado, S. L. Brock “Uniform Thin Films of CdSe and CdSe(ZnS) Core(shell) Quantum Dots by Sol-Gel Assembly: Enabling Photoelectrochemical Characterization and Electronic Applications”ACS Nano 2013, 7, 1215–1223 http://pubs.acs.org/doi/abs/10.1021/nn304563j

89. A. Hitihami-Mudiyanselage, K. Senevirathne, S. L. Brock “Assembly of Phosphide Nanocrystals Into Porous Networks: Formation of InP Gels and Aerogels”ACS Nano 2013, 7, 1163–1170 http://pubs.acs.org/doi/abs/10.1021/nn305959q

 

2012

88. J. N Freitas, J. P. C. Alves, L. Korala, S. L. Brock, A. F. Nogueira “Hybrid photovoltaic devices based on chalcogenide nanostructures”. Proceedings of SPIE, 2012, 847711-847711-11 http://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=1359692

87. K. K. Kalebaila, D. G. Georgiev, S. L. Brock “Lead Selenide Nanostructured Aerogels and Xerogels” Zeitschrift fuer Anorganische und Allgemeine Chemie, (Special Issue, Invited, Chalcogenides and Chalcogenidometalates: From Basic Research to Fundamental Applications) 2012, 638, 2598-2603. http://onlinelibrary.wiley.com/doi/10.1002/zaac.201200354/abstract

86. J. N Freitas, L. Korala, L. X Reynolds, S. A. Haque, S. L. Brock, A. F. Nogueira “Connecting the (quantum) dots: Toward hybrid photovoltaic devices based on chalcogenide gels” Physical Chemistry Chemical Physics, 2012, 14, 15180-15184. http://pubs.rsc.org/en/content/articlelanding/2012/cp/c2cp42998e

85. R. Seshadri, S. L. Brock, A. Ramirez, M. A. Subramanian, M. E. Thompson “Advances in the development and growth of functional materials: Toward the paradigm of materials by design” MRS Bulletin, 2012, 37, 682-690. http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8637546

84. S. Ganguly, C. Zhou, D. Morelli, J. Sakamoto, S. L. Brock “Synthesis and Characterization of Telluride Aerogels: Effect of Gelation on Thermoelectric Performance of Bi2Te3 and Bi2-xSbxTe3 Nanostructures”Journal of Physical Chemistry C, 2012, 116, 17431–17439. thttp://pubs.acs.org/doi/abs/10.1021/jp3055608

83. L. Korala, S. L. Brock “Aggregation Kinetics of Metal Chalcogenide Nanocrystals: Generation of Transparent CdSe (ZnS) Core (Shell) Gels”Journal of Physical Chemistry C, 2012, 116, 17110–17117. http://pubs.acs.org/doi/abs/10.1021/jp305378u

82. L. Korala, L. Li, S. L. Brock “Transparent conducting films of CdSe(ZnS) core(shell) quantum dot xerogels” Chemical Communications, 2012, 48, 8523-8525. http://pubs.rsc.org/en/Content/ArticleLanding/2012/CC/c2cc34188c

81. A. Wani, E. Muthuswamy, G. H. L. Savithra, G. Mao, S. L. Brock, D. Oupickỳ “Surface Functionalization of Mesoporous Silica Nanoparticles Controls Loading and Release Behavior of Mitoxantrone” Pharmaceutical Research 2012, 29, 2407-2418. http://link.springer.com/article/10.1007/s11095-012-0766-9

80. I. R. Pala, S. L. Brock “ZnS Nanoparticle Gels for Remediation of Pb2+ and Hg2+ Polluted Water”ACS Applied Materials & Interfaces 2012, 4, 2160-2167. http://pubs.acs.org/doi/abs/10.1021/am3001538

 

2011

79. M. Urdaneta, P. Stepanov, I. N. Weinberg, I. Pala and S. Brock “Porous Silicon-Based Quantum Dot Broad Spectrum Radiation Detector” Journal of Instrumentation 2011, 6, C01027-1-6. http://iopscience.iop.org/1748-0221/6/01/C01027/

76. E. Muthuswamy, G. H. L. Savithra, S. L. Brock “Synthetic Levers Enabling Independent Control of Phase, Size, and Morphology in Nickel Phosphide Nanoparticles” ACS Nano, 2011, 5, 2402-2411. http://pubs.acs.org/doi/abs/10.1021/nn1033357

77. P. Tian, Y. Zhang, K. Senevirathne, S. L. Brock, A. Dixit, G. Lawes, S. Billinge “Diverse Structural and Magnetic Properties of Differently Prepared MnAs Nanoparticles" ACS Nano, 2011, 5, 2970-2978. http://pubs.acs.org/doi/abs/10.1021/nn200020r

75. W. Dong, W. Rhine, G. Caggiano, O. R. Evans, G. Gould, J. White, J. Sharp, P. Gilbert, S. Ganguly, S. L. Brock “Characterization of Bismuth Telluride Aerogels for Thermoelectric Applications” Mater. Res. Soc. Symp. Proc., 2011, 1306,  DOI: 10.1557/opl.2011.475. http://journals.cambridge.org/action/displayAbstract?fromPage=online&aid=8207242

74. S. Ganguly, S. L. Brock, “Toward Nanostructured Thermoelectrics: Synthesis and Characterization of Lead Telluride Gels and Aerogels” Journal of Materials Chemistry, 2011, 21, 8800-8806. http://pubs.rsc.org/en/Content/ArticleLanding/2011/JM/c1jm11015b

73. Q. Yao, S. L. Brock “Porous CdTe Nanocrystal Assemblies: Ligation Effects on the Gelation Process and the Properties of Resultant Aerogels”  Inorganic Chemistry, 2011, 50, 9985-9992. http://pubs.acs.org/doi/abs/10.1021/ic201333y

72. E. Muthuswamy, S. L. Brock “Solid-State Phase Transformations in Solution: Templated Conversion of Nanoscale Nickel Phosphides” Chemical Communications, 2011, 47, 12334-12336. http://pubs.rsc.org/en/content/articlelanding/2011/cc/c1cc15198c

71. S. Ganguly, C. Zhou, D. Morelli, J. Sakamoto, C. Uher, S. L. Brock “Synthesis and Evaluation of Lead Telluride/Bismuth Antimony Telluride Nanocomposites for Thermoelectric Applications” Journal of Solid State Chemistry, 2011, 194, 3195-3201. http://www.sciencedirect.com/science/article/pii/S002245961100524X

 

2010

70. K. Somaskandan, G. M. Tsoi, L. E. Wenger, S. L. Brock “Ternary Heterostructured Phosphide Nanoparticles: MnP@InP” Journal of Materials Chemistry, 2010, 20, 375-380. http://pubs.rsc.org/en/Content/ArticleLanding/2010/JM/b919447a

69. Q. Yao, S. L. Brock, “Optical Sensing of Triethylamine by CdSe Aerogels” Nanotechnology, 2010, 21, 115502-1-10. http://iopscience.iop.org/0957-4484/21/11/115502/

68. I. R. Pala, I. U. Arachchige, D. G. Georgiev, S. L. Brock “Reversible Gelation of II-VI Nanocrystals: The Nature of Interparticle Bonding and the Origin of Nanocrystal Photochemical Instability” Angewandte Chemie International Edition, 2010, 49, 3661-3665. http://onlinelibrary.wiley.com/doi/10.1002/anie.201000034/abstract

67. S. Pawley, K. K. Kalebaila, I. Moudrakovski, J. A. Ripmeester, S. L. Brock “Pore Structure and Interconnectivity of CdS Aerogels and Xerogels by Hyperpolarized Xe NMR” Journal of Physical Chemistry, C, 2010, 114, 13187-13195. http://pubs.acs.org/doi/abs/10.1021/jp103157t

66. E. Muthuswamy, S. L. Brock “Oxidation Does Not (Always) Kill Reactivity of Transition Metals: Solution-Phase Conversion of Nanoscale Transition Metal Oxides to Phosphides and Sulfides” Journal of the American Chemical Society, 2010, 132, 15849-15851. http://pubs.acs.org/doi/abs/10.1021/ja106397b

65. R. Wang, L. Li, I. U. Arachchige, S. Ganguly, S. L. Brock, G. Mao “Nanoparticles Change the Ordering Pattern of n-Carboxylic Acids into Nanorods on HOPG” ACS Nano, 2010 4, 6687-6696. http://pubs.acs.org/doi/abs/10.1021/nn102184y

64. S. Bhattarai, E. Muthuswamy, A. Wani, M. Brichacek, A. L. Castañeda, S. L. Brock, D. Oupickỳ “Enhanced Gene and siRNA Delivery by Polycation-Modified Mesoporous Silica Nanoparticles Loaded with Chloroquine” Pharmaceutical Research 2010, 27, 2556-2568. http://www.springerlink.com/content/xl5l52308l077n57/

 

2009

63. Q. Yao, I. U. Arachchige, S. L. Brock “Expanding the Repertoire of Chalcogenide Nanocrystal Networks: Ag2Se Gels and Aerogels by Cation Exchange Reactions” Journal of the American Chemical Society, 2009, 131, 2800–2801. http://pubs.acs.org/doi/abs/10.1021/ja900042y

62. K. Senevirathne, R. Tackett, P. Kharel, G. Lawes, K. Somaskandan, S. L. Brock “Discrete, Dispersible MnAs Nanocrystals from Solution Methods: Phase Control on the Nanoscale and Magnetic Consequences” ACS Nano, 2009, 3, 1129-1138. http://pubs.acs.org/doi/abs/10.1021/nn900194f

61. H. Yu, Y. Liu, S. L. Brock “Tuning the Optical Band Gap of Quantum Dot Assemblies by Varying Network Density” ACS Nano, 2009, 3, 2000-2006. http://pubs.acs.org/doi/abs/10.1021/nn900456f

60. E. Muthuswamy, P. R. Kharel, G. Lawes, S. L. Brock “Control of Phase in Phosphide Nanoparticles Produced by Metal Nanoparticle Transformation: Fe2P and FeP” ACS Nano, 2009, 3, 2383-2393. http://pubs.acs.org/doi/abs/10.1021/nn900574r

 

2008

59. Y. You, K. K. Kalebaila, S. L. Brock, D. Oupickỳ “Temperature-Controlled Uptake and Release in PNIPAM-modified Mesoporous Silica Nanoparticles” Chemistry of Materials, 2008, 20, 3354-3359. http://pubs.acs.org/doi/abs/10.1021/cm703363w

58. C. M. Sweeney, K. L. Stamm, S. L. Brock “On the Feasibility of Phosphide Generation from Phosphate Reduction:  The Case of Rh, Ag, and Ir” Journal of Alloys and Compounds, 2008, 448, 122-127. http://www.sciencedirect.com/science/article/pii/S0925838806016252

57. H. Yu, Y. Liu, S. L. Brock “Synthesis of Discrete and Dispersible MoS2 Nanocrystals” Inorganic Chemistry, 2008, 47, 1428-1434. http://pubs.acs.org/doi/abs/10.1021/ic701020s

56. K. L. Stamm, S. L. Brock “Synthesis and Characterization of Fe3P Composite Nanorods Produced by Phosphate Reduction in Anodized Alumina Templates” Journal of Alloys and Compounds, 2008, 453, 476-481. http://www.sciencedirect.com/science/article/pii/S0925838806019785

55. H. Yu, R. Bellair, R. M. Kannan, S. L. Brock “Engineering Strength, Porosity, and Emission Intensity of Nanostructured Networks by Altering the Building-Block Shape” Journal of the American Chemical Society, 2008, 130, 5054-5055. http://pubs.acs.org/doi/abs/10.1021/ja801212e

54. K. Senevirathne, S. L. Brock “Recent Developments in Synthetic Approaches to Transition Metal Phosphide Nanoparticles for Magnetic and Catalytic Applications” Journal of Solid State Chemistry (invited contribution to a special issue on Nanoscience), 2008, 181, 1552-1559.  http://www.sciencedirect.com/science/article/pii/S0022459608001400

53. H. Yu, S. L. Brock “Effects of Nanoparticle Shape on the Morphology and Properties of Porous CdSe Assemblies (Aerogels)” ACS Nano, 2008, 2, 1563-1570. http://pubs.acs.org/doi/abs/10.1021/nn8002295

 

2007

52. I. U. Arachchige, S. L. Brock “Highly Luminescent Quantum Dot Monoliths” Journal of the American Chemical Society, 2007, 129, 1840-1841. http://pubs.acs.org/doi/abs/10.1021/ja066749c

51. I. U. Arachchige, S. L. Brock “Sol-Gel Methods for the Assembly of Metal-Chalcogenide Quantum Dots” Accounts of Chemical Research (invited, special issue, Sol Gel Materials and Chemistry), 2007, 40, 801-809. http://pubs.acs.org/doi/abs/10.1021/ar600028s

50. J. A. Aitken, G. Tsoi, L. E. Wenger, S. L. Brock "Phase Segregation of MnP in Chalcopyrite Dilute Magnetic Semiconductors: A Cautionary Tale" Chemistry of Material., 2007, 19, 5272-5278. http://pubs.acs.org/doi/abs/10.1021/cm071454z

49. K. Senevirathne, A. W. Burns, M. E. Bussell, S. L. Brock “Synthesis and Characterization of Discrete Nickel Phosphide Nanoparticles:  Effect of Surface Ligation Chemistry on Catalytic Hydrodesulfurization of Thiophene” Advanced Functional Materials, 2007, 17, 3933-3939. http://onlinelibrary.wiley.com/doi/10.1002/adfm.200700758/abstract

 

2006

48. K. K. Kalebaila, D. G. Georgiev, S. L. Brock “Synthesis and Characterization of Germanium Sulfide Aerogels” Journal of Non-Crystalline Solids, 2006, 352, 232-240. http://www.sciencedirect.com/science/article/pii/S0022309305007970

47. K. A. Gregg, S. C. Perera, G. Lawes, S. Shinozaki, S. L. Brock “Controlled Synthesis of MnP Nanorods:  The Effect of Shape Anisotropy on Magnetization” Chemistry of Materials, 2006, 18, 879-886. http://pubs.acs.org/doi/abs/10.1021/cm052080h

46. P. Arumugam, S. S. Shinozaki, R. Wang, G. Mao, S. L. Brock “From Ribbons to Nanodot Arrays:  Nanopattern Design through Reductive Annealing” Chemical Communications, 2006, 1121-1123. http://pubs.rsc.org/en/Content/ArticleLanding/2006/CC/b514595c

45. J. L. Mohanan, S. L. Brock “CdS Aerogels:  Effect of Concentration and Primary Particle Size on Surface Area and Opto-electronic Properties” Journal of Sol-Gel Science and Technology, (invited contribution to the special issue from the 2005 Conference on Sol-Gel Science), 2006, 40, 341-350. http://www.springerlink.com/content/m4616047188201m4/

44. I. U. Arachchige, S. L. Brock “Sol-Gel Assembly of CdSe Nanoparticles to form Porous Aerogel Networks” Journal of the American Chemical Society, 2006, 128, 7964-7971. http://pubs.acs.org/doi/abs/10.1021/ja061561e

43. S. L. Brock, I. U. Arachchige, K. K. Kalebaila “Metal Chalcogenide Gels, Xerogels and Aerogels,” Comments on Inorganic Chemistry (invited contribution), 2006, 27, 103-126. http://www.tandfonline.com/doi/abs/10.1080/02603590601084434

 

2005

42. J. L. Mohanan, I. U. Arachchige, S. L. Brock, “Porous Semiconductor Chalcogenide Aerogels,” Science, 2005, 307, 397-401. http://www.sciencemag.org/content/307/5708/397.full

41. K. Somaskandan, G. Tsoi, L. E. Wenger, S. L. Brock, “Isovalent Doping Strategy for Manganese Introduction into III-V Diluted Magnetic Semiconductor Nanoparticles:  InP:Mn,” Chemistry of Materials, 2005, 17, 1190-1198. http://pubs.acs.org/doi/abs/10.1021/cm048796e

40. J. A. Aitken, V. Ganzha-Hazen, S. L. Brock, “Solvothermal Synthesis of Cu3P via Reactions of Amorphous Red Phosphorus and a Variety of Copper Sources,” Journal of Solid State Chemistry, 2005, 178, 970-975. http://www.sciencedirect.com/science/article/pii/S0022459604005353

39. I. U. Arachchige, J. L. Mohanan, S. L. Brock, “Sol-gel Processing of Semiconducting Metal Chalcogenide Xerogels:  Influence of Dimensionality on Quantum Confinement Effects in a Nanoparticle Network,” Chemistry of Materials, 2005, 17, 6644-6650. http://pubs.acs.org/doi/abs/10.1021/cm0518325

38. B. Jayasekera, S. L. Brock, A. Y. H. Lo, R. W. Schurko, G.-A. Nazri, “Structure-Property Correlations in Solid Solutions of (CuI)8P12-xAsx, 2.4 ≤ x ≤ 6.6” Chemistry, A European Journal, 2005, 11, 3762-3772. http://onlinelibrary.wiley.com/doi/10.1002/chem.200400727/abstract

 

2004

37. D. Chen, R. Wang, I. Arachchige, G. Mao, S. L. Brock,Particle-Rod Hybrids: Growth of Arachidic Acid Molecular Rods from Capped Cadmium Selenide Nanoparticles,” Journal of the American Chemical Society, 2004, 126, 16290-16291. http://pubs.acs.org/doi/abs/10.1021/ja045011x

36. J. L. Mohanan, S. L. Brock, “A New Addition to the Aerogel Community: Unsupported CdS Aerogels with Tunable Optical Properties,” Journal of Non-Crystalline Solids (invited contribution to the special issue from the 7th International Symposium on Aerogels), 2004, 350, 1-8. http://www.sciencedirect.com/science/article/pii/S0022309304008592

35. B. Jayasekera, K. Somaskandan, S. L. Brock, “Liberation of Pnicogen Chains from Cu2P1.8As1.2I2:  Synthesis and Characterization of a New Polymer of P-As,” Inorganic Chemistry, 2004, 43, 6902-6904. http://pubs.acs.org/doi/abs/10.1021/ic0490223

34. S. L. Brock, S. C. Perera, K. L. Stamm, “Chemical Routes for Production of Transition Metal Phosphides on the Nanoscale: Implications for Advanced Magnetic and Catalytic Materials,” Chemistry-A European Journal, 2004, 10, 3364-3371 (invited Concepts paper). http://onlinelibrary.wiley.com/doi/10.1002/chem.200305775/abstract

 

2003

33. S. C. Perera, G. Tsoi, L. E. Wenger, S. L. Brock, “Synthesis of MnP Nanocrystals by Treatment of Metal Carbonyl Complexes with Phosphines: A New, Versatile Route to Nanoscale Transition Metal Phosphides,” Journal of the American Chemical Society, 2003, 125, 13960-13961. http://pubs.acs.org/doi/abs/10.1021/ja038037h

32. S. C. Perera, P. S. Fodor, G. Tsoi, L. Wenger, S. L. Brock, “Application of De-silylation Strategies to the Preparation of Transition Metal Pnictide Nanocrystals:  The Case of FeP,” Chemistry of Materials, 2003, 15, 4034-4038.

31. J. Mohanan, S. L. Brock, “Influence of Synthetic and Processing Parameters on the Surface Area, Speciation, and Particle Formation in Copper Oxide/Silica Aerogel Composites,” Chemistry of Materials, 2003, 15, 2567-2576.

30. S. C. Perera, S. L. Brock, “Effect of Precursor Salt on FeP Nanoparticle Formation,” Materials Research Society Symposium Proceedings, 2003, 755, DD5.9.1-DD5.9.6.

29. B. Jayasekera, S. L. Brock, “Ag Ion-Exchange Reactions of Cu2P3I2 and Cu2P1.8As1.2I2,” Materials Research Society Symposium Proceedings, 2003, 755, DD6.12.1-DD6.12.6.

28. K. L. Stamm, J. C. Garno, G.-y. Liu, S. L. Brock, “A General Methodology for the Synthesis of Transition Metal Pnictide Nanoparticles from Pnictate Precursors and its Application to Iron-Phosphorus Phases.” Journal of the American Chemical Society, 2003, 125, 4038-4039.

27. B. Jayasekera, J. A. Aitken, M. J. Heeg, S. L. Brock, “Towards an Arsenic Analog of Hittorf’s Phosphorus:  Mixed Pnicogen Chains in Cu2P1.8As1.2I2,” Inorganic Chemistry, 2003, 42, 658-660.

 

PUBLICATIONS FROM POSTDOCTORAL, GRADUATE AND UNDERGRADUATE RESEARCH

26. O. Giraldo, J. P. Durnad, H. Ramanan, K. Laubernds, S. L. Suib, M. Tsapatsis, S. L. Brock, M. Marquez, “Dynamic Organization of Inorganic Nanoparticles into Periodic Micrometer Scale Patterns,” Angewandte Chemie International Edition, 2003, 42, 2905-2909.

25. S. L. Brock, T. Shimojo, S. L. Suib, Y. Hayashi, H. Matsumoto, “Application of Non-Thermal Atmospheric Pressure AC Plasmas to the Carbon Dioxide Reforming of Methane,” Research on Chemical Intermediates, 2002, 28, 13-24.

24. G.-G. Xia, W. Tong, E. N. Tolentino, N.-G. Duan, S. L. Brock, J.-Y. Wang, S. L. Suib, T. Ressler, “Synthesis and Characterization of a Nanofibrous Sodium Manganese Oxide with a 2 x 4 Tunnel Structure,” Chemistry of Materials, 2001, 13, 1585-1592.

23. S. L. Brock; M. Sanabria, J. Nair, S. L. Suib, T. Ressler, “Tetraalkylammonium Manganese Oxide Gels:  Preparation, Structure, and Ion Exchange Properties,” Journal of Physical Chemistry B, 2001, 105, 5404-5410.

22. O. Giraldo; S. L. Brock; M. Marquez; S. L. Suib; H. Hillhouse; M. Tsapatsis, “Spontaneous Formation of Inorganic Helices,” Nature, 2000, 405, 38-38.

21. O. Giraldo; S. L. Brock; W. S. Willis; M. Marquez; S. L. Suib; S. Ching, “Manganese Oxide Thin Films with Fast Ion-Exchange Properties,” Journal of the American Chemical Society, 2000, 122, 9330-9331.

20. O. Giraldo, M. Marquez, S. L. Brock, S. L. Suib, H. Hillhouse, M. Tsapatsis, “Spontaneous Formation of Inorganic Helical Fibers and Rings,” Journal of the American Chemical Society, 2000, 122, 12158-12163.

19. F.-J. Spiess, X. Chen, S. L. Brock, S. L. Suib, Y. Hayashi, H. Matsumoto, “Destruction of Freons by the Use of High-Voltage Glow Plasmas,” Journal of Physical Chemistry A, 2000, 104, 11111-11120.

18. S. L. Brock, T. Shimojo, M. Marquez, C. Marun, S. L. Suib, H. Matsumoto and Y. Hayashi, “Factors Influencing the Decomposition of CO2 in AC Fan-Type Plasma Reactors:  Frequency, Waveform, and Concentration Effects,” Journal of Catalysis, 1999, 184, 123-133.

17.T. Ressler, S. L. Brock, J. Wong and S. L. Suib, “Multiple-Scattering EXAFS Analysis of Tetraalkylammonium Manganese Oxide Colloids,” Journal of Physical Chemistry B, 1999; 103; 6407-6420.

16. T. Ressler, S. L. Brock, J. Wong, S. L. Suib, “Structural Studies on Colloidal Tetraalkylammonium Manganese Oxides,” Journal of Synchrotron Radiation, 1999, 6, 728-730.

15. S. L. Brock, M. Sanabria, S. L. Suib, V. Urban, P. Thiyagarajan and D. I. Potter, “Particle Size Control and Self-Assembly Processes in Colloids of Nanocrystalline Manganese Oxide,” Journal of Physical Chemistry B, 1999, 103, 7416-7428.

14. T. Ozawa, M. M. Olmstead, S. L. Brock, S. M. Kauzlarich and D. M. Young, “Synthesis and Characterization of a New Compound with Alternating MnO22- and Zn2As22- Layers:  Ba2MnZn2As2O2,” Chemistry of Materials, 1998, 10, 392-396.

13. S. L. Brock, N. Duan, Z.-R. Tian, O. Giraldo, H. Zhou and S. L. Suib, “A Review of Porous Manganese Oxide Materials,” Chemistry of Materials, 1998, 10, 2619-2628.

12. S. L. Suib, S. L. Brock, M. Marquez, J. Luo, H. Matsumoto and Y. Hayashi, “Efficient Catalytic Plasma Activation of CO2, NO, and H2O,” Journal of Physical Chemistry B, 1998, 102, 9661-9666.

11. S. L. Brock, M. Marquez, S. L. Suib, Y. Hayashi and H. Matsumoto, “Plasma Decomposition of CO2 in the Presence of Metal Catalysts,” Journal of Catalysis, 1998, 180, 225-233.

10. S. L. Brock, N. P. Raju, J. E. Greedan, and S. M. Kauzlarich, "The Magnetic Structures of the Mixed Layer Pnictide Oxide Compounds Sr2Mn3Pn2O2 (Pn = As, Sb)," Journal of Alloys and Compounds, 1996, 237, 9-19.

9. S. L. Brock and S. M. Kauzlarich, "Structure-Property Relationships in a Series of Mixed Layer Pnictide Oxide Compounds:  A2Mn3Pn2O2 (A = Sr, Ba; Pn = P, As, Sb)," Journal of Alloys and Compounds, 1996, 241, 82-88.

8. S. L. Brock and S. M. Kauzlarich, "Pnictide Oxides:  A Unique Class of Compounds," Comments on Inorganic Chemistry, 1995, 17, 213-238.

7. S. L. Brock and S. M. Kauzlarich, "Unusual Layered Metal Oxides," CHEMTECH, 1995, 25:7, 18-22.

6. S. L. Brock, H. Hope, S. M. Kauzlarich, "Synthesis and Structure of a New Layered Pnictide Oxide Containing Close Mn-Mn Interactions: Ba2Mn2As2O," Inorganic Chemistry, 1994, 33, 405-406.

5. S. L. Brock, J. E. Greedan, and S. M. Kauzlarich, "A Test of the Application of Extended Hückel Calculations to the ThCr2Si2 and CaAl2Si2 Structure Types:  The Case of SrMn2P2 and BaMn2P2," Journal of Solid State Chemistry, 1994, 109, 416-418.

4. S. L. Brock, J. E. Greedan and S. M. Kauzlarich, "Resistivity and Magnetism of AMn2P2 (A = Sr, Ba):  The Effect of Structure Type on Physical Properties,"  Journal of Solid State Chemistry, 1994, 113, 303-311.

3. S. L. Brock, and S. M. Kauzlarich, "A2Zn3As2O2 (A = Sr, Ba): A Rare Example of Square Planar Zinc," Inorganic Chemistry, 1994, 33, 2491-2492

2. S. L. Brock, L. J. Weston, M. M. Olmstead and S. M. Kauzlarich, "Synthesis and Structure of A14AlSb11 (A = Ca, Sr, Ba)," Journal of Solid State Chemistry, 1993, 107, 513-523.

1. S. L. Brock and J. M. Mayer, "Oxygen Atom Transfer from a Phosphine Oxide to Tungsten (II) Complexes," Inorganic Chemistry, 1991, 30, 2138-2143.

 

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